Umicore CX96

Umicore CX96

Dichloro[1,1'-bis(di-tert-butylphosphino)ferrocene]palladium(II)

CAS Number: 95408-45-0

Product class: M-P, Homogeneous Catalysts, M-C, Bidentate Ligands, Ferrocenyl Ligands - Achiral

Reaction type: Cross Coupling Reactions with Arenes, Suzuki-Miyaura Coupling Reaction

Chemical properties

Chemical formula

C26H44Cl2FeP2Pd

Empirical formula

[Pd(dtbpf)Cl2]

Molecular weight

651.75

Metal

Pd

Theoretical metal content

16

Physical state

crystalline

Color

red

Metal purity

99.95

Applications & references

Reductive carbonylation of aryl halides as an alternative and mild route for the introduction of aldehyde functionality, which is mostly desired for fine chemical and pharmaceutical intermediates to open up the wide range of further possible transformations.

Reference: Org. Proc. Res. Dev. 2007, 11, 39. (DOI: 10.1021/op060193w)

 

Total synthesis of diacyl glycerolacyltransferase-1 (DGAT-1) inhibitor including an ambient temperature Suzuki−Miyaura coupling reaction. DGAT-1 is one of two isoforms which catalyze the final and committed step of triglyceride biosynthesis. This compound could play a decisive role in the development of obesity and insulin resistance. 

Reference: Org. Proc. Res. Dev. 2010, 14, 417 (DOI: 10.1021/op900310v)

 

High yielding Palladium catalyzed C-H arylation of electron-enriched heteroarenes with aryl bromides.

Reference: J. Org. Chem. 2010, 75, 6998. (DOI: 10.1021/jo101433g)

 

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