Umicore CX93

Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II)

CAS Number: 72287-26-4

Product class: M-P, Homogeneous Catalysts, Bidentate Ligands, Ferrocenyl Ligands - Achiral

Reaction type: Cross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, Carbonylation, Negishi Coupling Reaction, Stille Reaction, Suzuki-Miyaura Coupling Reaction, Oxidation

Applications & references

Reductive carbonylation of aryl halides as an alternative and mild route for the introduction of aldehyde functionality, which is mostly desired for fine chemical and pharmaceutical intermediates to open up the wide range of further possible transformations.

Reference: Org. Proc. Res. Dev. 2007, 11, 39. (DOI: 10.1021/op060193w), Synthesis 1996, 470 (DOI: 10.1055/s-1996-4246)

High yielding Palladium catalyzed C-H arylation of electron-enriched heteroarenes with aryl bromides.

Reference: J. Org. Chem. 2010, 75, 6998. (DOI: 10.1021/jo101433g)