(1,3-Divinyl-1,1,3,3-tetramethyldisiloxane)[1,1’-bis(diisopropylphosphino)ferrocene]palladium(0) toluene solution
CAS Number: 1708984-17-1
Product class: PGM Solutions, M-P, Homogeneous Catalysts, M-C, Vinylsiloxane Ligands, Ferrocenyl Ligands - Achiral, Vinylsiloxane Solutions
Reaction type: Amination, Buchwald-Hartwig Aminaton
WO2015059049 and foreign equivalents apply.
Applications & references
Highly selective monoarylation of primary anilines allows the sequential arylation of primary anilines with two different aryl bromides in one pot. This synthetic approach is operative in the preparation of high-purity triarylamines with large conjugated π-system as used in modern OLEDs as hole transport molecules.
Reference: Adv. Synth. Catal. 2016, 358, 1589. (DOI: 10.1002/adsc.201501160)