Umicore CX41

Umicore CX41

Dichloro(di-µ-chloro)bis[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]dipalladium(II)

CAS Number: 444910-17-2

Product class: M-P, Homogeneous Catalysts, N-Heterocyclic Carbene Ligands, M-C, IPr, Bidentate Ligands

Reaction type: Cross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, CH-Activation, Dehalogenation, Oxidation, Suzuki-Miyaura Coupling Reaction

Chemical properties

Chemical formula

C54H72N4Cl4Pd2

Empirical formula

[(IPr)PdCl2]2

Molecular weight

1131.84

Metal

Pd

Theoretical metal content

19

Physical state

powder

Color

orange

Metal purity

99.95

Legal information

US 6 316 380, WO 2004 014550 and foreign equivalents apply.

Applications & references

Intramolecular direct arylation of aryl chlorides.

Reference: Org. Lett. 2005, 7, 1857 (DOI: 10.1021/ol050501v)

 

Suzuki-Miyaura coupling reactions.

Reference: Chem. Comm. 2008, 3190 (DOI: 10.1039/B804695F )

 

Hydroarylation reaction.

Reference: US2009 0069580

 

Buchwald-Hartwig coupling reactions.

Reference: Synth. Comm. 2011, 41, 41 (DOI: 10.1039/B804695F) ; Org. Lett. 2002, 4, 2229 (DOI: 10.1021/ol0260831)

 

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